https://socictopen.socict.org/files/original/93e4afd968bcd04e8c206a906fe45a79.pdf 2acab5f73d75aa11d3d74c8d913ef058 Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Agricultura sostenible Description An account of the resource Dominio científico: Agricultura sostenible Text A resource consisting primarily of words for reading. Examples include books, letters, dissertations, poems, newspapers, articles, archives of mailing lists. Note that facsimiles or images of texts are still of the genre Text. Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Influence of Boron, Tungsten and Molybdenum Modifiers on Zirconia Based Pt Catalyst for Glycerol Valorization Creator An entity primarily responsible for making the resource Manuel Checa, Vicente Montes, Jesús Hidalgo-Carrillo, Alberto Marinas, Francisco J. Urbano Description An account of the resource The influence of boron, tungsten and molybdenum modifiers on zirconia-based Pt catalyst was studied for glycerol valorization. Zirconia modified supports were prepared by impregnation of ZrO2 with either boric, silicontungstic or phosphomolybdic acids to obtain supports with enhanced Br&#246;nsted acidic properties. The modified supports were subsequently impregnated with chloroplatinic acid to obtain Pt-based catalysts. Pt incorporation resulted in the increase in Lewis acidity of the solids, being more significant for the Pt//W/ZrO2 catalyst. Reduced Pt catalysts were tested for the liquid-phase glycerol hydrogenolysis, observing a synergistic effect between catalyst acid sites and metal function that proved to be crucial in glycerol hydrogenolysis. The Pt//W/ZrO2 catalyst was the most active catalyst in this reaction, being the only leading to 1,3-PDO (45% sel., 160 &#176;C) while Pt//Mo/ZrO2 is the best option for 1,2-PDO (49% sel., 180 &#176;C). Reusability studies carried out for Pt//W/ZrO2 showed that catalytic activity dropped after the first use, remaining constant for the second and subsequent ones. Selectivity to reaction products also changes during reuses. Therefore, the selectivity to 1,2 PDO increases in the first reuse in detriment to the selectivity to n-propanol whereas the selectivity to 1,3-PDO remains constant along the uses. This behavior could be associated to the lixiviation of W species and/or catalyst fouling during reaction runs. Date A point or period of time associated with an event in the lifecycle of the resource 2019 Subject The topic of the resource HPAs, Pt catalysts, acid zirconia, catalysts deactivation, catalysts stability, glycerol hydrogenolysis, glycerol valorization Identifier An unambiguous reference to the resource within a given context 10.3390/nano9040509 Source A related resource from which the described resource is derived Nanomaterials Publisher An entity responsible for making the resource available MDPI AG Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Chemistry Relation A related resource <a href="https://www.mdpi.com/2079-4991/9/4/509" target="_blank" rel="noreferrer noopener">https://www.mdpi.com/2079-4991/9/4/509</a>