Six Flux Model for the Central Lamp Reactor Applied to an External Four-Lamp Reactor

Six Flux Model for the Central Lamp Reactor Applied to an External Four-Lamp Reactor

Fernando J. Beltran, Javier Rivas, Juan-Fernando Garcia-Araya

One of the difficulties of establishing the intrinsic kinetics of photocatalytic oxidation processes is due to the complex mathematical formula used to determine the rate of photon absorption. To solve this problem, some models have been proposed and checked, such as the Six Flux Model (SFM) confirmed in central lamp photoreactors. External lamp photoreactors are also one of the most used configurations to study the photocatalytic oxidation of contaminants in water, and complex mathematical solutions have been reported to solve the rate of photon absorption. In this work, SFM Equations already reported for the central lamp photoreactor have been adapted to determine the rate of photon absorption in an external four-lamp photoreactor. The results obtained show slight differences from those of the Monte Carlo method. Additionally, once the rate of photon absorption was validated, the intrinsic rate constant and scavenging factor of the photocatalytic oxidation of some contaminant compounds from results already published have been determined.

2021

external lamp photoreactor, photocatalytic oxidation kinetics, scavenging factor, six-flux model, volumetric rate of photon absorption, water organic contaminants

10.3390/catal11101190

Catalysts

MDPI AG

Chemistry, Chemical technology